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A glass ball-and-stick model of a three-armed triethyl citrate molecule

ACTIVE

Triethyl Citrate

Triethyl Citrate

A citric acid based ingredient used in deodorants to help keep underarms smelling fresh by working on the way odour forms, rather than masking it.

Source

An ester of citric acid and ethanol

Used for

Underarm freshness

How it works

Freshness from citric acid.

Triethyl citrate is an ester made from citric acid, the acid of citrus fruits, and ethanol. It is a liquid, oily ingredient, and in cosmetics it is classed with the deodorising ingredients.

Underarm odour is not caused by sweat itself. Fresh secretions are odourless, and the smell forms when the bacteria that naturally live on underarm skin break them down into volatile odour molecules. Triethyl citrate works on this process: it is broken down by the skin's bacterial flora in place of body sweat, into substances with little odour.

Because it works on how odour forms rather than covering it with fragrance, it is used as an active ingredient in deodorants. It is also used in perfumes and as a softening ingredient in some hair and skin products.
  1. 01

    Helps keep underarms smelling fresh

  2. 02

    Works on the way odour forms, not just masking it

  3. 03

    Made from citric acid, the acid of citrus fruits

Questions

How does triethyl citrate help with odour?
Underarm odour forms when skin bacteria break down odourless secretions into volatile, smelly molecules. Triethyl citrate is broken down by the skin's bacterial flora instead of body sweat, into substances with little odour, so it works on the source of the smell. (James et al., 2013; COSMILE Europe)
Is triethyl citrate natural?
It is made from citric acid and ethanol, and the European cosmetic ingredient database lists its origin as synthetic or plant. (COSMILE Europe)
Why is it often paired with other ingredients in deodorants?
Deodorants can work in several ways: managing the bacteria behind odour, binding odour molecules, or adding fragrance. Triethyl citrate sits comfortably alongside other freshening ingredients, such as shikimic acid, a plant acid mainly obtained from star anise that a recent review lists among cosmetic ingredients with deodorising activity. (COSMILE Europe; Batory and Rotsztejn, 2022)

Where it comes from

Triethyl citrate is made by joining citric acid, the acid of citrus fruits, with ethanol. (PubChem)

In cosmetics it is listed as a fragrance functional ingredient and plasticiser, and it is grouped with the deodorising ingredients used in deodorants and foot care. It is also used as a softener in hairsprays and as an emulsifier in creams. (COSMILE Europe)